学位

• 理学博士（筑波大学）
• Ph.D（University of Tsukuba）

経歴

学歴

受賞

その他

論文

• Switching Photoluminescence Wavelength of Arylated Single‐walled Carbon Nanotubes by Utilizing Steric Hindrance in Reductive Arylation（2025-02-05） [DOI]
• Two-fold addition reaction of silylene to C60: structural and electronic properties of a bis-adduct（2024-05） [DOI]
• Photoreactions of Sc3N@C80 with Disilirane, Silirane, and Digermirane: A Photochemical Method to Separate Ih and D5h Isomers（2022-02） [DOI]
• Addition of S-Heterocyclic Carbenes to Fullerenes: Formation and Characterization of Dithiomethano-Bridged Derivatives（2019-04）
• Photoreactions of Sc3N@Ih-C80 and Lu3N@Ih-C80 with disilirane: Isolation and characterization of labile 1,2-adducts（2018-12）
• Back Cover: Preparation, Structural Determination, and Characterization of Electronic Properties of [5,6]- and [6,6]-Carbosilylated Sc3N@I-h-C-80 (Chem. Asian J. 12/2017)（2017-06） [DOI] [Web of Scientce]
• Preparation, Structural Determination, and Characterization of Electronic Properties of [5,6]- and [6,6]-Carbosilylated Sc3N@I-h-C-80（2017-06） [DOI] [Web of Scientce]
• Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu3N@I-h-C-80（2017-05） [DOI] [Web of Scientce]
• Photochemical addition of silirane to endohedral metallofullerene: Electronic properties of carbosilylated Sc3N@l(h)-C80（2016-02） [DOI] [Web of Scientce]
• Preparation, Structural Determination, and Characterization of Electronic Properties of Bis-Silylated and Bis-Germylated Lu3 N@Ih -C80.（2015-11） [DOI] [PubMed]
• Preparation, Structural Determination, and Characterization of Electronic Properties of Bis-silylated and Bis-germylated Lu3N@I-h-C-80（2015-11） [DOI] [Web of Scientce]
• Thermal Reactions of Fullerenes with Cyclic Organosilicon and Organogermanium Compounds: Silylation and Germylation of C-60 and C-70（2014-11） [DOI] [Web of Scientce]
• Thermal Reactions of C60 with Siliranes: Carbosilylation and Silylene Addition of Fullerenes（2014-01） [DOI] [Web of Scientce]
• Bis-Silylation of Lu3N@I-h-C-80: Considerable Variation in the Electronic Structures（2012-12） [DOI] [Web of Scientce]
• Analysis of Functionalization Degree of Single-Walled Carbon Nanotubes Having Various Substituents（2012-10） [DOI] [Web of Scientce]
• Synthesis of Silylene-Bridged Endohedral Metallofullerene Lu3N@Ih-C80（2012-09-18） [DOI]
• Synthesis of Silylene-Bridged Endohedral Metallofullerene Lu3N@I-h-C-80（2012-09） [DOI] [Web of Scientce]
• 化学修飾によるLa₂@C₈₀の電子アクセプター性制御（2011） [DOI] [CiNii Research]
• Thermal Carbosilylation of Endohedral Dimetallofullerene La-2@I-h-C-80 with Silirane（2010-12） [DOI] [Web of Scientce]
• Photochemical Addition of C-60 with Siliranes: Synthesis and Characterization of Carbosilylated and Hydrosilylated C-60 Derivatives（2010-09） [DOI] [Web of Scientce]
• Two-Step Alkylation of Single-Walled Carbon Nanotubes: Substituent Effect on Sidewall Functionalization（2010-03） [DOI] [Web of Scientce]
• A new method for separating the D-3 and C-2v isomers of C-78（2009） [DOI] [Web of Scientce]
• Location of the metal atoms in Ce-2@C-78 and its bis-silylated derivative（2008） [DOI] [Web of Scientce] [Othres link]
• Two-dimensional hopping motion of encapsulated La atoms in silylated La-2@C-80（2007） [DOI] [Web of Scientce] [Othres link]
• Characterization of the bis-silylated endofullerene Sc₃N@C ₈₀（2006） [DOI] [Web of Scientce]
• Preparation of Single-Walled Carbon Nanotubes-Organosilicon Hybrids and Their Enhanced Field Emission Properties（2006-01） [DOI]
• Synthesis and characterization of exohedrally silylated M@C-82 (M = Y and La)（2005-04） [DOI] [Web of Scientce]
• Chemical reactivities of the cation and anion of M@C-82 (M = Y, La, and Ce)（2005-02） [DOI] [Web of Scientce]
• M@C82 (M=Y, La, Ce) アニオン・カチオンの化学反応性（2005） [DOI] [CiNii Research] [Othres link]
• シラシクロプロパンによるC60の光ケイ素化（2005） [DOI] [CiNii Research]
• Chemical reactivity of Sc₃N@C₈₀ and La ₂@C₈₀（2005） [DOI]
• Positional control of encapsulated atoms inside a fullerene cage by exohedral addition（2005） [DOI] [Web of Scientce] [Othres link]
• Characterization of Ce@C-82 and its anion（2004-04） [DOI] [Web of Scientce]
• Characterization of Ce@C-82 and its anion（2004） [DOI] [Web of Scientce] [Othres link]
• Silylation of fullerenes with active species in photolysis of polysilane（2003-11） [DOI] [Web of Scientce]
• Synthesis and characterization of tetrakis-silylated C-60 isomers（2003-08） [DOI] [Web of Scientce]
• Synthesis and characterization of cyclic silicon compounds of fullerenes（2003-07） [Web of Scientce]
• One Step Synthesis of Highly-Pure Soluble Single-Walled Carbon Nanotubes（2003）
• Redox Properties of Carbosilylated and Hydrosilylated Fullerene Derivatives（2003）
• Photochemical Bissilylation of C70 with Disilane（2003）
• A comparison of the photochemical reactivity of N@C-60 and C-60: photolysis with disilirane（2003） [DOI] [Web of Scientce]
• Ionization and structural determination of the major isomer of Pr Γ₈₂（2002-07-10） [DOI]
• Location of the metal atoms in Ce2@C78 and its bis-silylated derivative（2002） [DOI] [Othres link]
• Endohedral fullerene ions: Synthesis, structure and reaction（2002） [Web of Scientce]
• Silylation of higher fullerenes（2002） [DOI]
• Novel photocycloaddition of aromatic ketones to cyclic oligosilanes（2001-12） [Web of Scientce]
• Silylene-transfer reactions of cyclic organosilanes induced by phenanthraquinone triplet（2001-11） [Web of Scientce]
• Photochemical cycloaddition of C-78 with disilirane（2001-10） [Web of Scientce]
• Structural determination of the La@C-82 isomer（2001-04） [DOI] [Web of Scientce]
• Photoinduced electron-transfer reactions between C-60 and cyclic disiliranes (c-R2Si-X-SiR2; X = SiR2, CH2, O, NPh, S)（2001-02） [Web of Scientce]
• Chemistry of endohedral metallofullerene ions（2001） [Web of Scientce]
• Chemistry of endohedral metallofullerene ions: Structural determination of the La@C-82 isomer（2001） [Web of Scientce]
• Photo-induced electron-transfer reactions of cyclic organosilanes and related compounds（2000-11） [Web of Scientce]
• C-60-sensitized bis-silylation of nitrile and carbonyl compounds with disilirane（2000-10） [Web of Scientce]
• Photochemical bis-silylation of C-60: synthesis of a novel C-60 main chain polysilane（2000-10） [Web of Scientce]
• A 3,4-benzo-1,2-germacyclobut-3-ene and related compounds. Palladium-catalyzed sigma-metathesis, dehydrogenative coupling and hydrogermylation of the Ge-Ge sigma-bond（2000-10） [Web of Scientce]
• La@C-82 anion. An unusually stable metallofullerene（2000-09） [DOI] [Web of Scientce]
• A first photochemical bis-germylation of C-60 with digermirane（2000-08） [DOI] [Web of Scientce]
• Silylene-transfer Reactions of Cyclic Organosilanes Induced by Phenanthraquinone Triplet（2000-07）
• Structures and ionization energies of some bis- and tris-（3, 4-dimetala-butyne-1, 4-diyl）s containing group 14 elements as key metal atoms: tetragermacycloocta-1,5-diyne, hexasilacyclododeca-1,5,9-triyne, hexagermacyclododeca-1, 5, 9-triyne, and related（2000-06） [Web of Scientce]
• Photoinduced electron-transfer reaction between C-60 and cyclic silicon compounds（2000-04） [Web of Scientce]
• Metal-free Bis-germylation: C60-Sensitized Reaction of Digermirane with Benzonitrile（2000）
• Novel metal-free bis-silylation: C-60-sensitized reaction of disilirane with benzonitrile（1999-11） [Web of Scientce]
• Endohedrally metal-doped heterofullerenes: La@C81N and La-2@C79N（1999-09） [Web of Scientce]
• Reactions of vinyldisilanes with ruthenium carbonyl（1999-08） [Web of Scientce]
• Photophysical and photochemical properties of bis-silylated C-60 derivatives（1999-08） [Web of Scientce]
• The silylfullerenes（1999-05）
• Photoinduced electron-transfer reaction of 7,8-disilabicyclo[2.2.2]octa-2,5-dienes（1999-02） [Web of Scientce]
• Reactions of vinyldisilanes with ruthenium carbonyl（1999） [DOI]
• Photochemical bissilylation of C-60 with disilane（1999-01） [Web of Scientce]
• Charge transfer complexes and electron transfer reaction of organosilicon and related compounds（1998-09） [Web of Scientce]
• Optical characteristics of ultrathin oligosilane films prepared by molecular beam deposition method（1998-08） [Web of Scientce]
• Endohedrally metal-doped heterofullerenes（1998） [Web of Scientce]
• C-13 and La-139 NMR studies of La-2@C-80: First evidence for circular motion of metal atoms in endohedral dimetallofullerenes（1997-08） [Web of Scientce]
• Photo-induced silylene-transfer reactions of cyclic organosilanes to phenanthraquinone（1997-08） [Web of Scientce]
• Silacyclopentadienylidene, the first silylene incorporated in a silole ring（1997-07） [Web of Scientce]
• Electron-transfer reaction of 1,2-disila-3,5-cyclohexadienes（1997-05） [Web of Scientce]
• Charge-transfer complex formation and photo-induced electron-transfer reaction of dibenzo-7-silabicyclo[2.2.1]hepta-2,5-dienes（1997-01） [Web of Scientce]
• Synthesis and properties of a strained germacycle having a Ge-Ge bond, 3,4-benzo-1,1,2,2-tetraethyl-1,2-digermacyclobut-3-ene（1996-04） [Web of Scientce]
• ELECTRONIC-PROPERTIES, POLYMERIZATION, AND CYCLOADDITION OF 3,4,7,8-TETRAGERMACYCLOOCTA-1,5-DIYNE AND RELATED-COMPOUNDS（1995-09） [Web of Scientce]
• REARRANGEMENT OF SILANORBORNADIENES VIA PHOTOINDUCED ELECTRON-TRANSFER（1995-08） [Web of Scientce]
• TETRACYANOETHYLENE-INDUCED CHLORINATIVE CLEAVAGE OF PERMETHYLATED OLIGOGERMANES WITH POLYHALOMETHANES（1995-03） [Web of Scientce]
• PHOTOCHEMICAL ISOMERIZATION OF 1-GERMA-2,4-CYCLOHEXADIENES（1994-10） [Web of Scientce]
• PREPARATION AND PROPERTIES OF 3,4,7,8-TETRAGERMACYCLOOCTA-1,5-DIYNE AND RELATED-COMPOUNDS（1994-08） [Web of Scientce]
• Solution-Phase far-UV Photolysis of Peralkylated mono-, di-, and tri-Germanes（1994） [DOI]
• Photochemical Reactions of cf3-substituted benzenes with tetraalkylated group 14 organometals（1994） [DOI]
• 1,1-DIMESITYL-1-SILACYCLOPENTA-2,4-DIENE - A STABLE CARBON-UNSUBSTITUTED SILOLE（1993-11） [Web of Scientce]
• PHOTOINDUCED NOVEL SILYLATION OF CF-3-SUBSTITUTED BENZENES WITH DISILANE AND TRISILANE（1993-04） [Web of Scientce]
• Reaction of singlet oxygen with disiliranes: Dioxygen insertion into Si-Si σ bonds（1993） [DOI]
• CYCLOREVERSION OF 2,3-DISILABICYCLO[2.2.2]OCTA-5,7-DIENES INDUCED BY ELECTRON-TRANSFER（1993-01） [Web of Scientce]
• PHOTOINDUCED ELECTRON-TRANSFER OXYGENATION OF 1,2-DISILETENE（1992-04） [Web of Scientce]
• FORMATION OF 1,2,3,6-DIOXADISILIN IN PHOTOINDUCED ELECTRON-TRANSFER OXYGENATION OF 1,2-DISILETENE（1991-11） [Web of Scientce]
• "Direct Observation of the Azetidinium Imide Intermediate in the [σ2+π2] addition of 1,24-Triazoline-3,5-dione to Disiliranes"（1991）
• SPECTROSCOPIC STUDIES ON CHARGE-TRANSFER PHOTOOXYGENATION OF DISILIRANES（1990-10） [Web of Scientce]
• SINGLET OXYGENATION OF OXADISILIRANES - SYNTHESES AND CRYSTAL-STRUCTURE OF 1,2,4,3,5-TRIOXADISILOLANES（1990） [DOI] [Web of Scientce]
• Formation of 1,2-dioxolane in the singlet oxygenation of a silicon-silicon σ-bond: peroxonium ion intermediate（1989） [DOI]
• REACTION OF SINGLET OXYGEN WITH THIIRANE - PEROXYSULFENIC ACID INTERMEDIATE AS A NEW OXIDIZING SPECIES（1988-01） [Web of Scientce]

その他業績

• Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds（2017-07） [DOI] [Web of Scientce]
• シリル化金属内包フラーレン誘導体の合成と物性解明（2012） [J-GLOBAL]
• 遷移金属錯体を用いた環状ケイ素化合物とC₆₀との反応（2011） [J-GLOBAL]
• 金属内包フラーレンLa₂@C₈₀とシラシクロプロパンの反応（2009） [J-GLOBAL]
• シラシクロプロパンによる金属内包フラーレンの化学修飾（2008） [J-GLOBAL]
• フラーレンと環状有機ケイ素化合物の光反応（2006） [J-GLOBAL]
• フラーレン類の光ケイ素化（2006） [J-GLOBAL]
• フラーレンとシラシクロプロパン類の光反応（2005） [J-GLOBAL]
• M@C₈₂(M=Y,La,Ce)アニオン・カチオンの化学反応性（2005） [J-GLOBAL]
• 光反応によるC₆₀-シラシクロプロパン付加体の合成（2004） [J-GLOBAL]
• 窒素内包フラーレンの光反応（2004） [J-GLOBAL]
• 金属内包フラーレンの分子変換（2002） [J-GLOBAL]
• Ce内包フラーレンの構造と反応性（2002） [J-GLOBAL]
• シリルフラーレンの合成と物性（2001） [J-GLOBAL]
• Photochemical cycloaddition of C76 with disilirane（2001）
• シリル化フラーレンのドックス挙動（2000） [J-GLOBAL]
• 熱的ビスシリル化反応（1999） [J-GLOBAL]
• C₆₀とオリゴシラン類の光反応（1999） [J-GLOBAL]
• 電気化学的ビスシリル化反応（1999） [J-GLOBAL]
• カルボニル化合物の光ビスシリル化反応（1999） [J-GLOBAL]
• フラーレンと有機ケイ素化合物の光反応（1998） [J-GLOBAL]
• ¹³C and ¹³⁹La NMR Study of La₂@C₈₀. The First Ecidence for Circular Motion of Metal Atoms in Endohedral Dimetallofullerene（1997） [DOI]
• Electron Transfer Oxygenation of Oxadisiliranes（1993） [DOI]
• DIRECT OBSERVATION OF AN AZETIDINIUM IMIDE INTERMEDIATE IN [PI(2) + SIGMA(2)] ADDITION OF 1,2,4-TRIAZOLINE-3,5-DIONE TO DISILIRANE（1991-07） [Web of Scientce]

講演・口頭発表等

• Photoreactions of Sc3N@Ih-C80 and Lu3N@Ih-C80 with Disilirane: Characterization of Labile 1,2-Adducts（2019-03）
• Photoreaction of Sc3N@Ih-C80 with Disilirane: Formation and Isomerization of 1,2-, 1,3-, and 1,4-Adducts（2018-03）
• Photoreactions of Cyclic Organosilanes with Trimetallic Nitride Template Endohedral Metallofullerenes（2017-02）
• Photochemical Addition of Siliranes to Sc3N@Ih-C80: Interconversion of the [6,6]- and [5,6]-Adducts（2017-02）
• Photoreactions of Trimetallic Nitride Template Endohedral Metallofullerenes with Digermirane（2016-02）
• Preparation, Structural Determination, and Characterization of Electronic Properties of Carbosilylated Sc3N@Ih-C80（2016-02）
• Reactions of Endohedral Metallofullerenes with Silacyclopropanes: Mono-silylation and Carbosilylation of Lu3N@Ih-C80（2016-02）
• Reactions of Trimetallic Nitride Template Endohedral Metallofullerenes with Silacyclopropanes（2015-02）
• Addition Reactions of Trimetallic Nitride Template Endohedral Metallofullerenes with Disilirane and Digermirane（2015-02）
• Synthesis, Structural Determination and Characterization of Electronic Properties of Bis-Germylated Sc3N@Ih-C80 and Lu3N@Ih-C80（2014-09）
• 不飽和化合物の光誘起電子移動型ビスシリル化反応（1998-09）

書籍等出版物

作品等

共同研究・競争的資金等の研究課題

メディア報道

産業財産権

所属学協会

• フラーレン・ナノチューブ・グラフェン学会
• 光化学協会
• ケイ素化学協会
• 日本化学会

委員歴

担当経験のある科目

• 化学結合と構造
• 化学概論第一
• 材料化学
• 基礎科学実験B2
• 無機物質化学特論
• 現代化学
• 化学概論第二
• 基礎化学実験
• 基礎科学実験B1
• 基礎科学実験B
• 化学概論第一（クラス4）
• 現代化学
• 現代化学
• 化学概論第二
• 基礎化学実験
• 無機物質化学特論
• 現代化学
• 化学概論第二
• 基礎化学実験
• 基礎科学実験B
• 化学概論第一（クラス4）
• 化学概論第一
• 化学結合と構造
• 化学結合と構造
• 基礎科学実験B
• 現代化学
• K課程総合コミュニケーション科学
• K課程総合コミュニケーション科学
• Chemistry Laboratory

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